Buy Hydroxylimine HCl Cas 7803-49-8

Purity of Buy Hydroxylimine HCl Cas 7803-49-8
99%
Appearance
Odorless white crystalline solid. Sinks and mixes with water.
Synonyms
hydroxylamine,freebase; hydroxylaminefree-base; NH2OH; Oxammonium; Oxyammonia; FH-50; FH-50TM; HYDROXYLAMINE
IUPAC Name
hydroxylamine

Buy Hydroxylimine HCl Cas 7803-49-8

Buy Hydroxylimine HCl Cas 7803-49-8

 

Hydroxylamine (also known as hydroxyammonia) is an inorganic compound with the chemical formula NH2OH. The compound exists as hygroscopic colorless crystals.[4] Hydroxylamine is almost always provided and used as either an aqueous solution or, more often, as one of its salts, such as hydroxylammonium sulfate, a water-soluble solid. Buy Hydroxylimine HCl Cas 7803-49-8

Hydroxylamine and its salts are consumed almost exclusively to produce Nylon-6. The oxidation of NH3 to hydroxylamine is a step in biological nitrification.[5]

History

Hydroxylamine was first prepared as hydroxylammonium chloride in 1865 by the German chemist Wilhelm Clemens Lossen (1838-1906); he reacted tin and hydrochloric acid in the presence of ethyl nitrate.[6] It was first prepared in pure form in 1891 by the Dutch chemist Lobry de Bruyn and by the French chemist Léon Maurice Crismer (1858-1944).[7][8] The coordination complex ZnCl2(NH2OH)2 (zinc dichloride di(hydroxylamine)), known as Crismer’s salt, releases hydroxylamine upon heating. Buy Hydroxylimine HCl Cas 7803-49-8

 

Product
Hydroxylamine-[15N] hydrochloride

Hydroxylamine-[15N] hydrochloride is the labelled analogue of Hydroxylamine Hydrochloride, which acts as a mild reducing agent in various organic and inorganic chemical reactions. Synonyms: Hydroxylamine-(15)N HCl; Hydroxylamine chloride-15N. Grade: 98% by CP; 98% atom 15N. CAS No. 40711-48-6. Molecular formula: ClH4[15N]O. Mole weight: 70.48. BOC Sciences 2

Hydroxylamine-[d3] deuteriochloride

Hydroxylamine-[d3] deuteriochloride. Synonyms: Hydroxylamine-d3 deuteriochloride. Grade: 98% by CP; 98% atom D. CAS No. 15588-23-5. Molecular formula: D4ClNO. Mole weight: 73.52. BOC Sciences 2

hydroxylamine dehydrogenase

The enzymes from the nitrifying bacterium Nitrosomonas europaea and the methylotrophic bacterium Methylococcus capsulatus are hemoproteins with seven c-type hemes and one specialized P-460-type heme per subunit. The enzyme converts hydroxylamine to nitrite via an enzyme-bound nitroxyl intermediate. While nitrite is the main product, the enzyme from Nitrosomonas europaea can produce nitric oxide as well. Group: Enzymes. Synonyms: HAO (ambiguous); hydroxylamine oxidoreductase (ambiguous); hydroxylamine oxidase (misleading). Enzyme Commission Number: EC 1.7.2.6. CAS No. 9075-43-8. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-1621; hydroxylamine dehydrogenase; EC 1.7.2.6; 9075-43-8; HAO (ambiguous); hydroxylamine oxidoreductase (ambiguous); hydroxylamine oxidase (misleading). Cat No: EXWM-1621. Creative Enzymes

Hydroxylamine hydrochloride

1kg Pack Size. Group: Amines, Building Blocks, Organics. Formula: H3NO.Hcl. CAS No. 5470-11-1. Prepack ID 21834412-1kg. Molecular Weight 69.49. See USA prepack pricing. Molekula Americas

Hydroxylamine hydrochloride

Hydroxylamine hydrochloride is a selective monoamine oxidase (MAO) inhibitor used for inhibiting of platelet aggregation. Hydroxylamine hydrochloride is an intermediate of organic synthesis [1]. Uses: Scientific research. Group: Signaling pathways. CAS No. 5470-11-1. Pack Sizes: 10 mM * 1 mL; 500 mg; 1 g; 5 g; 10 g. Product ID: HY-Y0882. MedChemExpress MCE

Hydroxylamine hydrochloride

Hydroxylamine hydrochloride. Synonyms: Hydroxylammonium chloride. CAS No. 5470-11-1. Pack Sizes: 100, 500 g in poly bottle. Product ID: CDC10-0053. Molecular formula: NH2OH HCl. Category: Antioxidant Cosmetic Chemicals. Product Keywords: Cosmetic Ingredients; Antioxidant Cosmetic Chemicals; Hydroxylamine hydrochloride; CDC10-0053; 5470-11-1; NH2OH HCl; Hydroxylammonium chloride; 226-798-2; MFCD00051089; 5470-11-1. Purity: 0.98. Color: White to off-white. EC Number: 226-798-2. Physical State: Powder, crystals or chunks. Quality Level: 200. Storage: Store at 15°C to 25°C. Application: Powerful reducing agent. Converts aldehydes and ketones to oximes, and acid chlorides to hydroxamic acids. Used as catalyst, swelling agent, and copolymerization inhibitor. Melting Point: 155-157 °C (dec.) (lit.). Density: 1.67 g/mL at 25 °C(lit.). CD Formulation

Hydroxylamine Hydrochloride

Hydroxylamine Hydrochloride. Grades: ACS. CAS No. 5470-11-1. Pack Sizes: Gram Quantities: 125 gm , 6 x 125 gm, 6 x 500 gm, 2.5 kg. Order Number: 13093. Prochem Inc

www.prochemonline.com
Hydroxylamine Hydrochloride

Hydroxylamine Hydrochloride. Molecular Formula  NH2OH HCl. Chemical Reagents Cater Chemicals Corp.

Cater Chemicals Corp. Illinois IL
Hydroxylamine Hydrochloride-15N

Hydroxylamine Hydrochloride-15N. Group: Biochemicals. Alternative Names: Hydroxyammonium Chloride-15N; Hydroxylamine Chloride-15N; Hydroxylamine Chlorohydrate-15N; Hydroxylammonium Chloride-15N; Oxammonium Hydrochloride-15N. Grades: Highly Purified. CAS No. 40711-48-6. Pack Sizes: 10mg. US Biological Life Sciences. USBiological 3

Worldwide
Hydroxylamine Hydrochloride 99+% ACS

Hydroxylamine hydrochloride is a monomoamine oxidase inhibitor. It is used to prepare oximes and hydroxmic acids in organic synthesis. It acts as a copolymerization inhibitor. It can be used to remove bromine and polybromide from a solution during extraction of lignin from lignocellulosic biomass. It is key starting material for the preparation of pharmaceuticals and agrochemicals. It plays a vital role in rubber and plastic industries as an antioxidant, a vulcanization accelerator and a radical scavenger. It is also used as a color stabilizer and emulsion additive in color films. Group: Biochemicals. Alternative Names: Hydroxylammonium chloride. Grades: ACS Grade. CAS No. 5470-11-1. Pack Sizes: 100g, 250g, 1Kg, 2.5Kg, 5Kg. Molecular Formula: NH2OH·HCl, Molecular Weight: 69.49. US Biological Life Sciences. USBiological 5

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Hydroxylamine Hydrochloride, Reagent Grade, 100 g

Formula: NH2OH HCl. F. W: 69. 49. Storage Code: Blue; toxic. Grades: chem-grade reagent. CAS No. No. 5470-11-1. Product ID: 868290. — SOLD FOR EDUCATIONAL USE ONLY — Carolina Biological Supply Company

Hydroxylamine,o-[(1,1-dimethylethyl)diphenylsilyl]-

Hydroxylamine,o-[(1,1-dimethylethyl)diphenylsilyl]-. Uses: Designed for use in research and industrial production. Product Category: Siloxanes. Appearance: Transparent liquid. CAS No. 103587-51-5. Molecular formula: C16H21NOSi. Mole weight: 271.43. Purity: 95%+. Product ID: ACM103587515. Alfa Chemistry — ISO 9001:2015 Certified. Categories: O-(TERT-BUTYLDIPHENYLSILYL)HYDROXYLAMINE. Alfa Chemistry. 3

Hydroxylamine-o-sulfonic acid

Hydroxylamine-o-sulfonic acid. CAS No. 2950-43-8. Richman Chemical

Pennsylvania PA
Hydroxylamine-O-sulfonic acid

100g Pack Size. Group: Building Blocks, Inorganic Chemicals. Formula: H3NO4S. CAS No. 2950-43-8. Prepack ID 77461217-100g. Molecular Weight 113.09. See USA prepack pricing. Molekula Americas

Hydroxylamine-O-sulfonic Acid

Hydroxylamine-O-sulfonic Acid is used in the synthesis of quinolones for the benzodiazepine site of GABAA receptors. Also used in the inhibition of PCDD as well as PCB formation in co-combustion. Group: Biochemicals. Alternative Names: Amidoperoxymonosulfuri c Acid (HOS(O)2ONH2); Amidosulfonic Peracid; Aminomonopersulfuric Acid; Ammonia-N-oxide-O-sulfonic Acid Betaine; HAOS; O-Sulfohydroxylamine; Hydroxylaminesulfonic Acid; Permonosulfamic Acid; Sulfoperamidic Acid; Sulfuric Acid Monoazanyl Ester. Grades: Highly Purified. CAS No. 2950-43-8. Pack Sizes: 10g. US Biological Life Sciences. USBiological 3

Worldwide
hydroxylamine oxidase (cytochrome)

The enzyme from the heterotrophic nitrifying bacterium Paracoccus denitrificans contains three to five non-heme, non-iron-sulfur iron atoms and interacts with cytochrome c556 and pseudoazurin. Under anaerobic conditions in vitro only nitrous oxide is formed. Presumably nitroxyl is released and combines with a second nitroxyl to give nitrous oxide and water. When oxygen is present, nitrite is formed. Group: Enzymes. Synonyms: HAO (ambiguous); hydroxylamine oxidoreductase (ambiguous); hydroxylamine oxidase (misleading). Enzyme Commission Number: EC 1.7.3.6. CAS No. 9075-43-8. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-1628; hydroxylamine oxidase (cytochrome); EC 1.7.3.6; 9075-43-8; HAO (ambiguous); hydroxylamine oxidoreductase (ambiguous); hydroxylamine oxidase (misleading). Cat No: EXWM-1628. Creative Enzymes

Hydroxylamine phosphate

Hydroxylamine phosphate. Uses: Designed for use in research and industrial production. Additional or Alternative Names: HYDROXYLAMINE PHOSPHATE;HYDROXYLAMINE PHOSPHATE SALT (3:1);HYDROXYLAMMONIUM PHOSPHATE;HAP;hydroxylammonium phosphate (3:1);Hydroxyamine phosphate;Hydroxylamine phosphate salt (3:1),98%;RRB2. Product Category: Heterocyclic Organic Compound. CAS No. 20845-01-6. Molecular formula: H12N3O7P. Mole weight: 197.08. Product ID: ACM20845016. Alfa Chemistry — ISO 9001:2015 Certified. Alfa Chemistry. 5

hydroxylamine reductase

A flavoprotein. Reduced pyocyanine, methylene blue and flavins act as donors for the reduction of hydroxylamine. May be identical to EC 1.7.2.1, nitrite reductase (NO-forming). Group: Enzymes. Synonyms: hydroxylamine (acceptor) reductase; ammonia:(acceptor) oxidoreductase. Enzyme Commission Number: EC 1.7.99.1. CAS No. 37256-42-1. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-1634; hydroxylamine reductase; EC 1.7.99.1; 37256-42-1; hydroxylamine (acceptor) reductase; ammonia:(acceptor) oxidoreductase. Cat No: EXWM-1634. Creative Enzymes

hydroxylamine reductase (NADH)

Also acts on some hydroxamates. Group: Enzymes. Synonyms: hydroxylamine reductase; ammonium dehydrogenase; NADH-hydroxylamine reductase; N-hydroxy amine reductase; hydroxylamine reductase (NADH2); NADH2:hydroxylamine oxidoreductase. Enzyme Commission Number: EC 1.7.1.10. CAS No. 9032-6-8. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-1603; hydroxylamine reductase (NADH); EC 1.7.1.10; 9032-06-8; hydroxylamine reductase; ammonium dehydrogenase; NADH-hydroxylamine reductase; N-hydroxy amine reductase; hydroxylamine reductase (NADH2); NADH2:hydroxylamine oxidoreductase. Cat No: EXWM-1603. Creative Enzymes

Hydroxylamine Solution

HYDROXYLAMINE SOLUTION, 50% in water, Formula: H3NO. CAS No. 7803-49-8. Noah Chemicals San Antonio, Texas. ISO 9001:2015 Certified. Request a Quote Today! Noah Chemicals

Texas TX
Hydroxylamine solution 50 wt. % in H2O

100ml Pack Size. Group: Analytical Reagents, Building Blocks, Catalysts, Inorganic Chemicals. Formula: H3NO. CAS No. 7803-49-8. Prepack ID 90027344-100ml. Molecular Weight 33.03. See USA prepack pricing. Molekula Americas

Hydroxylamine sulfate

1kg Pack Size. Group: Amines, Building Blocks, Inorganic Chemicals. Formula: H6N2O2 · H2O4S. CAS No. 10039-54-0. Prepack ID 46597701-1kg. Molecular Weight 164.13832. See USA prepack pricing. Molekula Americas

Hydroxylamine sulfate

Hydroxylamine sulfate. Group: Biochemicals. Grades: Highly Purified. CAS No. 10039-54-0. Pack Sizes: 25g, 50g, 100g, 250g, 500g. US Biological Life Sciences. USBiological 7

Worldwide
Hydroxylamine Sulfate

Hydroxylamine Sulfate. Group: Polymers. Alfa Chemistry Materials 4

Hydroxylamine sulfate 99+%

Hydroxylamine sulfate 99+%. Group: Biochemicals. Grades: Reagent Grade. CAS No. 10039-54-0. Pack Sizes: 1Kg, 5Kg, 25Kg. US Biological Life Sciences. USBiological 5

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Hydroxylamine Sulphate 10039-54-0

Hydroxylamine Sulphate 10039-54-1. SUPPLIERS TO BUSINESS CUSTOMERS ONLY. Redox

North America & APAC
Hydroxylamine-Wang resin

Hydroxylamine-Wang resin. Synonyms: 4-H2N-OCH2-Ph-O-CH2-Ph-polymer. Molecular formula: C14H15NO2. Mole weight: 229.27. BOC Sciences 10

aromatic-hydroxylamine O-acetyltransferase

Transfers the N-acetyl group of some aromatic acethydroxamates to the O-position of some aromatic hydroxylamines. Group: Enzymes. Synonyms: aromatic hydroxylamine acetyltransferase; arylhydroxamate acyltransferase; arylhydroxamate N,O-acetyltransferase; arylhydroxamic acid N,O-acetyltransferase; arylhydroxamic acyltransferase; N,O-acetyltransferase; N-hydroxy-2-acetylaminofluorene N-O acyltransferase. Enzyme Commission Number: EC 2.3.1.56. CAS No. 52660-15-8. Storage: Store it at +4 ?C for short term. For long term storage, store it at -20 ?C?-80 ?C. Form: Liquid or lyophilized powder. EXWM-2235; aromatic-hydroxylamine O-acetyltransferase; EC 2.3.1.56; 52660-15-8; aromatic hydroxylamine acetyltransferase; arylhydroxamate acyltransferase; arylhydroxamate N,O-acetyltransferase; arylhydroxamic acid N,O-acetyltransferase; arylhydroxamic acyltransferase; N,O-acetyltransferase; N-hydroxy-2-acetylaminofluorene N-O acyltransferase. Cat No: EXWM-2235

Structure

Hydroxylamine and its N-substituted derivatives are pyramidal at nitrogen, with bond angles very similar to those of amines. The most stable conformation of hydroxylamine has the NOH anti to the lone pair on nitrogen, seeming to minimize the repulsion between the nitrogen and oxygen lone pairs. [10]

Production

Hydroxylamine or its salts (salts containing hydroxylammonium cations [NH3OH]+) can be produced via several routes but only two are commercially viable. It is also produced naturally as discussed in a section on biochemistry.

From nitric oxide

NH2OH is mainly produced as its sulfuric acid salt, hydroxylammonium sulfate ([NH3OH][SO4]), by the hydrogenation of nitric oxide over platinum catalysts in the presence of sulfuric acid.[11]

2 NO + 3 H2 + H2SO4 → [NH3OH]2[SO4]

Raschig process

Another route to NH2OH is the Raschig processaqueous ammonium nitrite is reduced by HSO−3 and SO2 at 0 °C to yield a hydroxylamido-N,N-disulfonate anion:

[NH4]+[NO2] + 2 SO2 + NH3 + H2O → [NH4]2[HON(SO3)2]

This ammonium hydroxylamine disulfonate anion is then hydrolyzed to give hydroxylammonium sulfate:

[NH4]2[HON(SO3)2] + 2 H2O → [HONH3]2SO4

Other methods

Julius Tafel discovered that hydroxylamine hydrochloride or sulfate salts can be produced by electrolytic reduction of nitric acid with HCl or H2SO4 respectively:[12][13]

HNO3 + 3 H2 → NH2OH + 2 H2O

Hydroxylamine can also be produced by the reduction of nitrous acid or potassium nitrite with bisulfite:

 

Hydroxylamine hydrochloride can be used as a reactant: Buy Hydroxylimine HCl Cas 7803-49-8

  • in the synthesis of primary amides from aldehydes in the presence of cesium carbonate (Cs2CO3) as a catalyst.
  • in the conversion of alicyclic /aliphatic carbonyl compounds and the aromatic aldehydes into corresponding oximes.
  • in the one-pot synthesis of nitriles from aldehydes in the presence of sodium sulfate (anhyd) and sodium bicarbonate catalysts.
  • It can also be used as a reducing agent in the preparation of single-layer reduced graphene oxide (RGO) sheets and films. Buy Hydroxylimine HCl Cas 7803-49-8
MAO inhibitor; inhibits platelet aggregation.
Hydroxylamine hydrochloride (Hydroxylammonium chloride) participates in the synthesis of 1,2,4-oxadiazoles,[1] secondary amides and tertiary amides.[2]
Hydroxylamine hydrochloride (NH2OH.HCl) is a hygroscopic salt widely used as a reactant in electrophilic substitution reactions, oxidation, and reduction reactions. It is also used in the synthesis of nitriles, pyrazoles, isoxazoles, nitrones, and pyridine. Buy Hydroxylimine HCl Cas 7803-49-8
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal – Acute Tox. 4 Oral – Aquatic Acute 1 – Aquatic Chronic 2 – Carc. 2 – Eye Irrit. 2 – Met. Corr. 1 – Skin Irrit. 2 – Skin Sens. 1 – STOT RE 2 Oral

target_organs

spleen

Storage Class

4.1A – Other explosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicab

Hydroxylamine hydrochloride

Cat. No.: HY-Y0882 Purity: 99.12%
Data Sheet 

 

Handling Instructions  Technical Support

 

Hydroxylamine hydrochloride is a selective Monoamine oxidase (MAO) inhibitor used for inhibiting of platelet aggregation. Hydroxylamine hydrochloride is an intermediate of nitrogen cycle in aerobic ammonium oxidizers microorganisms, such as ammonium oxidizing bacteria (AOB), ammonium oxidizing archaea (AOA) and complete ammonium oxidizing bacteria (comammox). Hydroxylamine hydrochloride impacts NO and N2O emissions by aerobic ammonium oxidizers microorganisms and inhibits nitrite oxidizing bacteria (NOB) activity. Buy Hydroxylimine HCl Cas 7803-49-8

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